I'm having the same problem where newly added VMs to the datastore cluster failed to show up in ~StorageDrsConfig.VmConfig. One way I've found to get them to show up is to enable/disable storage DRS from vSphere Client on the datastore cluster. For some reason, after doing that from the vSphere GUI, the VMs show up then in ~StorageDrsConfig.VmConfig. I tried using Set-DatastoreCluster to change the sdrsautomationlevel to manual / disabled, but no luck in getting the VMs to show up. So far, only after editing the datastore cluster settings from vSphere client. Not sure if it might be an issue with the vCenter Server not passing the information along or what. I'd be curious to know what versions you're using. I'm using ESXi 5.1U1, vCenter Server 5.1U1, and PowerCLI 5.1 release 1.
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